SMOKE CENTURION

Faresetninger (CLP)

H222

Kode

Setning

H222

Extremely flammable aerosol

Tilleggsinformasjon

PRESSURIZED CONTAINER: MAY BURST IF HEATED. 2.3 OTHER HAZARDS: NONE. 3. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS PRODUCT AS SUPPLIED: AEROSOL. 3.1 MIXTURES: HAZARDOUS INGREDIENT (S) CAS NO. SW/W BUTANE 106-97-8 50 - 100 PROPANE 74-98-6 10 - 25 ETHANOL 64-17-5 0 - 5 3.2 ADDITIONAL INFORMATION: NONE. 4. SECTION 4: FIRST AID MEASURES 4.1 DESCRIPTION OF FIRST AID MEASURES: INHALATION: ITF BREATHING IS DIFFICULT, REMOVE VICTIM TO FRESH ATR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. SKIN CONTACT: WASH WITH PLENTY OF WATER. BYE CONTACT: FLUSH BYES WITH WATER FOR AT LEAST 15 MINUTES WHILE HOLDING EYELIDS OPEN. INGESTION: UNLIKELY ROUTE OF EXPOSURE. 4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: NONE ANTICIPATED. 4,3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED: UNLIKELY TO BE REQUIRED BUT IF NECESSARY TREAT SYMPTOMATICALLY. 5. SECTION 5: FIRE-FIGHTING MEASURES PRESSURIZED CONTAINER: MAY BURST IF HEATED. 5.1 EXTINGUISHING MEDIA: SUITABLE EXTINGUISHING MEDIA: EATINGUISH WITH CARBON DIOXIDE, DRY CHEMICAL, FOAM OR WATER SPRAY. UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER JET. 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE: HEATING MAY CAUSE PRESSURE RISE WITH RISK OF BURSTING. 5.3 ADVICE FOR FIRE-FIGHTERS: FIRE FIGHTERS SHOULD WEAR COMPLETE PROTECTIVE CLOTHING INCLUDING SELF-CONTAINED BREATHING APPARATUS. IF IT IS SAFE TO DO SO, CONTAINERS SHOULD BE REMOVED FROM FIRE AREA BECAUSE THEY ARE LIKELY TO RUPTURE UNDER FIRE CONDITIONS. 6. SECTION 6: ACCIDENTAL RELEASE MEASURES THE PRODUCT IS AN AEROSOL. IT IS UNLIKELY TO PRESENT SPILLAGE OR LEAKAGE HAZARD. IN CASE OF RUPTURE, RELEASED CONTENT SHOULD BE CONTAINED AS ANY OTHER SOLVENT SPILL. 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: ENSURE ADEQUATE VENTILATION. WEAR SUITABLE GLOVES AND EYE/FACE PROTECTION. 6.2 ENVIRONMENTAL PRECAUTIONS: DO NOT RELEASE LARGE QUANTITIES INTO THE SURFACE WATER OR INTO DRAINS. 6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP: COLLECT MECHANICALLY AND DISPOSE OF ACCORDING TO SECTION 13. ADSORB SPILLAGES ONTO SAND, EARTH OR ANY SUITABLE ADSORBENT MATERIAL. TRANSFER TO A LIDDED CONTAINER FOR DISPOSAL OR RECOVERY. CONTAINERS MUST NOT BE PUNCTURED OR DESTROYED BY BURNING, EVEN WHEN EMPTY. 6.4 REFERENCE TO OTHER SECTIONS: SEE ALSO SECTION: 8, 13. 7. SECTION 7: HANDLING AND STORAGE 7.1 PRECAUTIONS FOR SAFE HANDLING: KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. NO SMOKING. DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT SPRAY ON A NAKED FLAME OR ANY INCANDESCENT MATERIAL. PROVIDE ADEQUATE VENTILATION. DO NOT EAT, DRINK OR SMOKE DURING WORK. WASH HANDS THOROUGHLY AFTER HANDLING. 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES: OBSERVE OFFICIAL REGULATIONS ON STORING PACKAGINGS WITH PRESSURIZED CONTAINERS. STORAGE TEMPERATURE: PRESSURIZED CONTAINER: MAY BURST IE HEATED. PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING 122 DEG. F (50 DEG. C). STORAGE LIFE: STABLE UNDER NORMAL CONDITIONS. INCOMPATIBLE MATERIALS: NONE ANTICIPATED. 7.3 SPECIFIC END USE(S): SMOKE SIMULATION. 8. SECTION 8: EXPOSURE CONTROLS/ PERSONAL PROTECTION 8.1 CONTROL PARAMETERS: 8.1.1 OCCUPATIONAL EXPOSURE LIMITS: SUBSTANCE CAS NO. LTEL (8 HR LTEL (8 HR STEL NOTE TWA PPM) TWA MG/M3) (PPM) (MG/M3) BUTANE 106-97-8 800 1900 NIOSH PROPANE 74-98-6 1000 1800 NIOSH 1000 1800 PEL (OSHA) ETHANOL 64-17-5 1000 1900 NIOSH 1000 1900 PEL (OSHA) SOURCE: NIOSH = NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY & HEALTH OSHA = OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION 8.2 APPROPRIATE ENGINEERING CONTROLS: PROVIDE ADEQUATE VENTILATION. 8.3 INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT (PPE): EYE/FACE PROTECTION: IF EYE CONTACT IS LIKELY: WEAR PROTECTIVE EYEWEAR (GOGGLES, FACE SHIELD, OR SAFETY GLASSES). SKIN PROTECTION (HAND PROTECTION/OTHER) WEAR SUITABLE GLOVES IF PROLONGED SKIN CONTACT IS LIKELY. GLOVES: NITRILE RUBBER, NBR. RESPIRATORY PROTECTION: NO PERSONAL RESPIRATORY PROTECTION EQUIPMENT NORMALLY REQUIRED. HANDLING OF LARGER AMOUNTS: IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT. THERMAL HAZARDS: NOT APPLICABLE. 9. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9,1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES: APPEARANCE: AEROSOL. COLOR: COLORLESS. ODOR: CHARACTERISTIC. ODOR THRESHOLD: NOT DETERMINED. PH: NOT DETERMINED. MELTING POINT/FREEZING POINT: NOT DETERMINED. INITIAL BOILING POINT AND BOILING RANGE: -47.4 DEG. F (-44 DEG. C) FLASH POINT: <32 DEG. F (<0 DEG. C) EVAPORATION RATE: NOT AVATLABLE. FLAMMABILITY (SOLID, GAS): EXTREMELY FLAMMABLE. UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: EXPLOSIVE LIMIT RANGES: 1.5 - 15.0 VOL-% VAPOR PRESSURE: 62.4 PSIG (4.3 BAR) @ 68 DEG. F DENSITY: 36.2 LB/FT3 (0.58 G/CM3) @ 68 DEG. F VAPOR DENSITY: NOT DETERMINED. RELATIVE DENSITY: NOT DETERMINED. SOLUBILITY (IES): IMMISCIBLE WITH WATER. PARTITION COEFFICIENT N-OCTANOL/WATER: NOT DETERMINED. IGNITION TEMPERATURE: 689 DEG. F (365 DEG. C) AUTO-IGNITION TEMPERATURE: PRODUCT IS NOT SELFIGNITING. DECOMPOSITION TEMPERATURE: NOT DETERMINED. KINEMATIC VISCOSITY: NOT DETERMINED. EXPLOSIVE PROPERTIES: NOT EXPLOSIVE. OXIDIZING PROPERTIES: NOT OXIDIZING. 9.2 OTHER INFORMATION: ORGANIC SOLVENT - CONTENT: 96.4% 10. SECTION 10: STABILITY AND REACTIVITY 10.1 REACTIVITY: STABLE UNDER NORMAL CONDITIONS. 10.2 CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS. 10.3 POSSIBILITY OF HAZARDOUS REACTIONS: STABLE UNDER NORMAL CONDITIONS. 10.4 CONDITIONS TO AVOID: HEAT AND DIRECT SUNLIGHT. 10.5 INCOMPATIBLE MATERIALS: NONE ANTICIPATED. 10.6 HAZARDOUS DECOMPOSITION PRODUCT(S): NONE KNOWN. 11. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 INFORMATION ON TOXICOLOGICAL EFFECTS: 11.1.1 MIXTURES: ACUTE TOXICITY: LOW ACUTE TOXICITY. TRRITATION: NON-IRRITANT. CORROSIVITY: NOT CLASSIFIED. SENSITIZATION: IT IS NOT A SKIN SENSITIZER. REPEATED DOSE TOXICITY: NONE ANTICIPATED. CARCINOGENICITY: NO EVIDENCE OF CARCINOGENICITY. MUTAGENICITY: THERE IS NO EVIDENCE OF MUTAGENIC POTENTIAL. TOXICITY FOR REPRODUCTION: NONE ANTICIPATED. ASPIRATION HAZARD: NONE ANTICIPATED. 11.2 OTHER INFORMATION: NONE. 12. SECTION 12: ECOLOGICAL INFORMATION 12.1 TOXICITY: LOW TOXICITY TO AQUATIC ORGANISMS. 12.2 PERSISTENCE AND DEGRADABILITY: THE PRODUCT IS READILY BIODEGRADABLE. UNLIKELY TO PERSIST. 12.3 BIOACCUMULATIVE POTENTIAL: THE PRODUCT HAS NO POTENTIAL FOR BIOACCUMULATION. 12.4 MOBILITY IN SOIL: IMMISCIBLE WITH WATER. THE PRODUCT IS PREDICTED TO HAVE LOW MOBILITY IN SOIL. 12.5 OTHER ADVERSE EFFECTS: NONE. 13. SECTION 13: DISPOSAL CONSIDERATIONS 13.1 WASTE TREATMENT METHODS: RECYCLE ONLY COMPLETELY EMPTIED PACKAGING. CONTAINERS MUST NOT BE PUNCTURED OR DESTROYED BY BURNING, EVEN WHEN EMPTY. NON-EMPTIED AEROSOL: DISPOSE OF WASTES IN AN APPROVED WASTE DISPOSAL FACTLITY. DO NOT LANDFILL. 13.2 ADDITIONAL INFORMATION: DISPOSAL SHOULD BE IN ACCORDANCE WITH LOCAL, STATE OR NATIONAL LEGISLATION. 14. SECTION 14: TRANSPORT INFORMATION 14.1 UN NUMBER: UN 1950 ADR, IMDG, IATA: 14.2 UN PROPER SHIPPING NAME: 1950 AEROSOLS ADR: AEROSOLS IMDG: AEROSOLS, FLAMMABLE TATA: 14.3 TRANSPORT HAZARD CLASS (ES): ADR: CLASS / CLASSIFICATION: 2 5F GASES LABEL: 2.1 IMDG, IATA: CLASS / DIVISION: 2.1 LABEL: 2.1 14.4 PACKING GROUP: ADR, IMDG, IATA: NONE. 14.5 ENVIRONMENTAL HAZARDS: MARINE POLLUTANT: NO. 14.6 SPECIAL PRECAUTIONS FOR USER: WARNING: GASES. KEMLER CODE: IMDG EMS: F-D, S-U 14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE: NOT APPLICABLE. 14.8 ADDITIONAL INFORMATION: ADR: LIMITED QUANTITY (LQ): IL ADR TRANSPORT CATEGORY: 2 TUNNEL RESTRICTION CODE: NOT APPLICABLE IN LIMITED QUANTITIES. LIMITED QUANTITY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT IMDG: LIMITED QUANTITY (LQ): IL LIMITED QUANTITY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT TATA: LIMITED QUANTITY (LQ): IL LIMITED QUANTITY MARKING FOR PACKAGES PREPARED FOR AIR TRANSPORT CLASS 2.1, FLAMMABLE GASES UN "MODEL REGULATION": UN 1950, ABROSOLS, 2.1 US: ORM-D WHEN TRANSPORTED IN LIMITED QUANTITIES (<30 KG OR 66 LB GROSS WEIGHT). 15. SECTION 15: REGULATORY INFORMATION 15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE SUBSTANCE OR MIXTURE: 15.1.1 OSHA: TOXIC AND HAZARDOUS SUBSTANCES (29 CFR 1910; SUBPART 2): LISTED: PROPANE (CAS NO.: 74-98-6) LISTED: ETHANOL (CAS NO.: 64-17-5) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS (40 CFR 61.01): ALL CHEMICALS ARE NOT LISTED. 15.1.2 TITLE III CONSOLIDATED LIST OF LISTS: LISTED: BUTANE (CAS NO.: 106-97-8) LISTED: PROPANE (CAS NO.: 74-98-6) CLEAN AIR ACT SECTION 112(R) THRESHOLD QUANTITY: 10000 15.1.3 OSPAR LIST OF CHEMICALS FOR PRIORITY ACTION: ALL CHEMICALS ARE NOT LISTED. 15.1.4 STATE RIGHT TO KNOW LISTS: BUTANE (CAS NO.: 106-97-8): NEW JERSEY, PENNSYLVANIA, MASSACHUSETTS, RHODE ISLAND. PROPANE (CAS NO.: 74-98-6): NEW JERSEY, PENNSYLVANTA, MASSACHUSETTS. ETHANOL (CAS NO.: 64-17-5): NEW JERSEY, PENNSYLVANTA, MASSACHUSETTS. 15.1.5 TSCA (TOXIC SUBSTANCE CONTROL ACT): ALL CHEMICALS LISTED. 15.1.6 PROPOSITION 65 (CALIFORNIA): ALL CHEMICALS ARE NOT LISTED. 15.1.7 CAA 602 - OZONE DEPLETING SUBSTANCES (ODS): ALL CHEMICALS ARE NOT LISTED. 16. SECTION 16: OTHER INFORMATION THE FOLLOWING SECTIONS CONTAIN REVISIONS OR NEW STATEMENTS: 1-16. NEPA: HEALTH 1 FIRE 4 INSTABILITY 0 HMIS: HEALTH 1 FLAMMABILITY 4 PHYSICAL HAZARDS 0 LEGEND: LTEL: LONG TERM EXPOSURE LIMIT STEL: SHORT TERM EXPOSURE LIMIT NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH PEL: PERMISSIBLE EXPOSURE LIMITS CAA: CLEAN AIR ACT OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OSPAR: OSLO AND PARIS CONVENTION ADR: ACCORD EUROPEEN ELATIVE AU TRANSPORT INTERNATIONAL DES MARCHANDISES DANGEREUSES PAR ROUTE (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD) IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS TATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION DISCLAIMERS: THE INFORMATION IS BASED ON THE BEST KNOWLEDGE OF SDI AND ITS ADVISORS AND IS GIVEN IN GOOD FAITH, BUT WE CANNOT GUARANTEE ITS ACCURACY, RELIABILITY OR COMPLETENESS AND THEREFORE DISCLAIM ANY LIABILITY FOR LOSS OR DAMAGE ARISING OUT OF USE OF THIS DATA. SINCE CONDITIONS OF USE ARE OUTSIDE THE CONTROL OF THE COMPANY AND ITS ADVISORS WE DISCLAIM ANY LIABILITY FOR LOSS OR DAMAGE WHEN THE PRODUCT IS USED FOR PURPOSES OTHER THAN IT IS INTENDED. Revision Date 3.1 22/07/2015

2.1 Klassifisering av stoffet eller stoffblandingen

THE SUBSTANCE OR MIXTURE: US CFR 1910.1200: FLAM., AEROSOL 1: EXTREMELY FLAMMABLE AEROSOL. 2.2 LABEL ELEMENTS